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Beilstein J. Org. Chem. 2016, 12, 172–178, doi:10.3762/bjoc.12.19
Graphical Abstract
Scheme 1: Dual-gold-catalysed hydrophenoxylation of alkynes.
Scheme 2: Exploring the functional group tolerance. Reaction conditions: 1a (0.50 mmol, 1 equiv), 2a–o (0.55 ...
Scheme 3: Hydrophenoxylation using polyphenols. Reaction conditions: 1a (1 mmol, 2 equiv), 2p–s (0.50 mmol, 1...
Scheme 4: Hydrophenoxylation of (un)symmetrical alkynes. Reaction conditions: 1b–k (0.50 mmol, 1 equiv), 2t (...
Scheme 5: Regioselective hydrophenoxylation of unsymmetrical alkynes. Reaction conditions: 1l–p (1 equiv), 2a...
Beilstein J. Org. Chem. 2012, 8, 1637–1643, doi:10.3762/bjoc.8.187
Figure 1: [Pd(NHC)(cin)Cl] catalysts examined in direct arylation.
Scheme 1: Synthesis of [Pd(IPr*Tol)(cin)Cl] (4).
Figure 2: Molecular structure of 4. H atoms were omitted for clarity. Selected bond lengths (Å) and angles (°...
Figure 3: Previously reported catalytic systems in the direct arylation of benzothiophene (6).